Headlining the stylish arrivals at the star-studded event were bold Rita Ora, loudmouth Ashley Roberts, Rochelle Humes, Emily Atack and AJ Odudu.
Hot Right Now creator Rita, 31, revealed her toned figure in a sheer black strappy dress that revealed her skimpy underwear underneath.
Rita turned heads in the off-the-shoulder dress, which skimmed over her fit physique and was teamed with stilettos and jewels.
Rita wore her dirty blonde tresses in loose waves around her shoulders and opted for bronzed makeup as she worked her magic on the red carpet.
Also making an appearance, 36-year-old Pussycat Doll Ashley left little to the imagination in a daring silver dress that showed off her ample assets as she posed up a storm on the red carpet.
Unbelievable: Hot Right Now creator Rita, 31, showed off her toned figure in a sheer black strappy dress that revealed her skimpy panties underneath
Confident: Rita grabbed attention in her off-the-shoulder gym top for the glitzy event
Hot look: She posed looking back over her shoulder for some of the snaps where she dazzled with her blonde locks falling over her shoulders
Glow: Rita highlighted her beautiful features and flawless complexion with dewy makeup
Perfect smile: Rita beamed as she posed for the cameras and showed off her perfect complexion
Beauty: She flashed the camera a sultry look as she posed inside the venue
Ashley made sure all eyes were on her in the number which fell below her navel and was translucent in another racy element to the look.
To complete her sexy look she elevated her height with matching heels and a bright bag while wearing her blonde tresses in curly waves and opting for bright make-up.
Elsewhere, presenter Rochelle put one foot down in a cleavage-baring black dress, which she teamed with a tassel bag and strappy heels.
Wow! Pussycat Doll Ashley, 36, left little to the imagination in a daring silver dress that revealed her ample assets as she posed up a storm on the red carpet
Bold: Ashley made sure all eyes were on her in the number which skimmed below her navel and was translucent in another racy look
TV star Emily Atack also had her toned and tanned pins in a black and silver mini dress which she teamed with huge heels and a bouncy blonde hairdo.
Meanwhile, former Strictly star AJ stunned in a blue and white dress which she teamed with a black bag as she posed up a storm.
Also in attendance were pregnant Katherine Ryan, Rachel Stevens, Edith Bowman, Anne Marie and Myleene Klass, all of whom looked stunning in their stylish outfits.
Glamorous: To complete her sexy look she elevated her height with matching heels and a shiny bag, while wearing her blonde tresses in curly waves and opting for bright make-up
Teen: Ashley sported a wet-look hairdo and perfect makeup
The Glamor Awards is an annual awards show hosted by Glamor magazine.
The Woman of the Year Awards honor “outstanding and inspiring” women from a variety of fields including entertainment, business, sports, music, science, medicine, education and politics.
Previous winners include Nicole Kidman, Naomi Campbell, Angelina Jolie, Lady Gaga and Victoria Beckham.
Radiant: Rochelle wore her dark tresses in a sleek cropped do and opted for flawless make-up with a soft lip gloss
Deborah Joseph, European Editorial Director at Glamour, said: “Shooting women who are changing the game in their field and challenging the status quo, our Glamor Women of the Year event is back, celebrating feminism in all its forms and corners of the sphere.
“Celebrating women who are making an incredible difference is one of the best parts of leading Glamor in Europe, so I’m thrilled that Woman of the Year will put that spotlight on it.”
The Women of the Year Awards also celebrate new talent, whether it’s rising stars or activists running incredible campaigns, such as one of last year’s winners, Amika George, who successfully campaigned for free period products to be made available in England in 2020 .
Gorgeous: TV star Emily Atack also had her toned and tanned pins in a black and silver lined mini dress
Bronzed goddess: Teamed her thigh-skimming dress with towering heels and a bouncy blonde blowout
Natural beauty: Emily looked stunning wearing her blonde tresses in loose waves while accessorizing with silver earrings
Working the room: She was the center of attention as she posed inside the event
Siblings: Rita posed with sister Elena at the event wearing a backless black mini dress
Golden Girl: Rita glowed as she headed in and out of the rain
It comes after earlier this month Emily Atack reportedly split from boyfriend Liam McGough, just two months after she went Instagram official with him.
The star is understood to have recently split with the former Big Brother contestant and tree surgeon, 37.
A source told the Sun: “Emily and Liam have been friends for a long time and were together for seven months but have sadly decided to split.
“They kept their relationship private for a while and only went public when news broke that they were together.
She worked it: She made sure all eyes were on her in the clingy dress she wore with silver and black heels
Accessories: She wore silver earrings to complete her look
Happy: She couldn’t stop smiling as she posed up a storm on the red carpet
New look: She sported a quirky new hair style
Motherhood: Katherine is currently expecting her second child with husband Bobby Kootstra
Couple: Catherine cuddled up to her husband Bobby who was wearing a cream jacket
Posing up a storm: Katherine wore her blonde tresses with a chic outfit and opted for a red lip
“Unfortunately, they decided they were better off as friends and broke up a few days ago, but everything is very amicable.”
MailOnline has contacted Emily’s representatives for comment.
Emily went Instagram official with new boyfriend Liam in August as she cozied up to him during a sunny lunch date in the great outdoors.
The Inbetweeners star’s social media milestone further cemented her relationship with the former reality star, with the loved-up pair posing for a selfie at a lavish brunch.
Tanned: Rachel looked red carpet ready in her gorgeous sparkly gown
Finishing off her look: Myleene accessorized perfectly with a gold clutch bag
Makeup: She looked radiant and opted for a pale pink lip
Goddess: Girls Aloud star Nicola Roberts looked gorgeous in a white dress with silver details
Flawless: She wore her red tresses in an up-do and opted for cool makeup to highlight her complexion
Liam was a housemate on the 2007 series of Big Brother where he finished in third place, losing to winner Brian Belo.
Emily has been linked to a number of men in recent months, including comedian and former Strictly Come Dancing contestant Seann Walsh and footballer Jack Grealish, 26.
TV star and Manchester City footballer Jack are said to have enjoyed a secret six-week fling while still with girlfriend Sasha Atwood – something the pair have vehemently denied.
Plunging: Meanwhile Frankie wore a smart black suit teamed with chunky boots
Daring! She sported her new darker brows and added a pop of color with a red lip
All smiles: Frankie looked in high spirits as she posed up a storm for the cameras
Kooky: Anne Marie wore a red and white jacket and skirt which she paired with chunky black boots
Rude! She chewed gum as she posed for snaps on the red carpet
It comes after Rita opened up about her love for husband Taika Waititi in a rare interview after secretly tying the knot earlier this summer.
The singer insists she’s hooked on the 47-year-old director and hinted she’s planning another big wedding in London for her friends and family.
Pop star Rita – who has never explicitly confirmed the marriage, although her close friends have confirmed it – says she was inspired by her mother Vera and father Besnik – in her search for love after learning from their strong relationship for more since 30 years.
She poses with confidence: Louise Redknapp was also in attendance and showed off her legs in a black dress
Gorgeous! Made In Chelsea star Georgia Toffolo looked gorgeous in a nude dress
Slinky: She showed off her figure in the figure-hugging number which looked perfect on her
Thigh split: Dina Usher-Smith wowed in a leg-baring brown dress
Sultry: The sheer number showed off her toned figure and was teamed with gold heels to accentuate her height
She told Jaime Winstone’s Greatest Night Ever podcast: “I’m in love. I’m very much in love. I’m in love, I’m in love, amen!
“But I also love love. I’ve always believed in it so much and I’ve always felt that I’ve always wanted the fairy tale and that’s what I grew up loving.’
Of her mum and dad, she added: ‘My parents have been together for over 30 years, so for me it’s always been about love and finding a partner and all that, so I’m really glad I did.
Here is! Sex And The City star Kim Cattrall showed off some leg in a strapless black and silver dress.
Stunning: Jasmine Sanders looked incredible in a navy blue satin dress worn with gold strappy heels
Stepping out: She teamed her gorgeous dress with a small silver bag and wore her dark ribbons.
Duo: Jasmine Sanders aka Golden Barbie and Rita Ora attend Glamor Women Of The Year Awards 2022 Drinks Reception
Serious faces! They looked great…